RFBR Project No. 05-03-32259 "Molecular sorption as a new method of controlling ionic conductivity in cyanometallates". Project supervisor – Е.V. Polyakov
Molecular sorption as a new method of controlling ionic conductivity in cyanometallates
Experimental study of the mechanism of ion-exchange and molecular sorption of molecules of alkaline and alkaline-earth metal compounds solvated by p,d-element cyanoferrates (II,III) from solutions, as well as structural transformations occurring during this process in the bulk and on the surface of a solid phase, and changes in the proton groupings will allow us to find out energy and spatial features of molecular sorption as a process of ordering/disordering of sorbed molecules. The data to be obtained will be used to elucidate the physicochemical reasons for the appearance of superionic conductivity in molecular-sorption cyanoferrate systems, which were first discovered by the project team.
